2015
T.Taniike, K.Goto, M.Terano
Polyolefins Journal, 2015, 2, 57-63
Active Site Nature of Magnesium Dichloride-Supported Titanocene Catalysts in Olefin Polymerization
2014
S.Poonpong, S.Dwivedi, T.Taniike, M.Terano
Macromolecular Chemistry and Physics, 2014, 215, 1721-1727.
Structure-performance relationship for dialkyldimethoxysilane as external donor in stopped-flow propylene polymerization using Ziegler-Natta catalyst
S.Dwivedi, T.Taniike, M.Terano
Macromolecular Chemistry and Physics, 2014, 215, 1698-1706
Understanding chemical and physical transformation of Ziegler-Natta catalyst at initial stage of polymerization kinetics: Key role of alkylaluminium in the catalyst activation process
A.Thakur, S.Poonpong, M.Terano, T.Taniike
Macromolecular Reaction Engineering, 2014, 8, 766-770
New Quenching Method for the Improvement of Large-Scale Stopped-Flow Technique
K.Kaneko, N.Yadav, K.Takeuchi, B.Maira, M.Terano, T.Taniike
Composites Science and Technology, 2014, 102, 120-125
Versatile Strategy for Fabrication of Polypropylene Nanocomposites with Inorganic Network Structures based on Catalyzed in-situ Sol-Gel Reaction during Melt Mixing
W.Yang, T.Taniike, M.Terano, Y.Chen, W.Sun
Journal of the Brazilian Chemical Society, 2014, 25, 2244-2250
Ethylene Polymerization by 2-methyl-8-(benzimidazol)quinolyliron(II) Pre-catalyst: A DFT Understanding its Chain Propagation and Transfer
Y.Fukuyama, M.Senda, T.Kawai, S.Kuroda, M.Toyonaga, T.Taniike, M.Terano
Journal of Thermal Analysis and Calorimetry, 2014, 117, 1397-1405
The effect of the addition of polypropylene-grafted SiO2 nanoparticle on the thermal conductivity of isotactic polypropylene
T.Taniike, M.Toyonaga, M.Terano,
Polymer, 55,1012-1019,2014.
Polypropylene-Grafted Nanoparticles as a Promising Strategy for Boosting Physical Properties of Polypropylene-Based Nanocomposites
K.Takeuchi, M.Terano, T.Taniike,
Polymer, 2014,55,1940-1947
Sol-gel synthersis of nano-sized silica in confined amorphous space of polypropylene: impact of nano-level structures of silica on physical properties of resultant nanocomposites
2013
T.Taniike, I.Katada, M.Terano
Long-term stabilization of polypropylene-based materials via molecular encapsulation with hyperbranched polymer
9th International Symposium on Weatherability, Tokyo Japan, Mar. 28-29, 2013.Oral
M.Terano, T.Taniike
Recent Achievements of Stopped-Flow Technique for Heterogeneous Olefin Polymerization
Asian Polyolefin Workshop 2013, Beijing, China, Oct. 15-19, 2013. Invited Lacture
M.Toyonaga, T.Taniike, M.Terano
A novel approach for improved mechanical properties of polypropylene-based nanocomposites using precisely designed polypropylene-grafted nanosilica
Asian Polyolefin Workshop 2013, Beijing, China, Oct, 15-19, 2013. Poster
Y.Zeng, T.Taniike, M.Terano,
Design of novel homogeneous Phillips catalyst with uniform active species and support
Asian Polyolefin Woekshop 2013. Beijing, China, Oct, 15-19, 2013, Poster
K.Goto, T.Taniike, M.Terano,
Macromolecular Chemistry and Physics, 214, 1011-1018, 2013.
Dual-Active-Site Nature of Magnesium Dichloride-Supported Cyclopentadienyl Titanium Chloride Catalysts Switched by an Activator in Propylene Polymerization
S.Takahashi, T.Wada, T.Taniike, M.Terano,
Catalysts, 3, 137-147, 2013.
Precise Active Site Analysis for TiCl3/MgCl2 Ziegler-Natta Model Catalyst Based on Fractionation and Statistical Methods
Y.Zeng, A.Matta, S.Dwivedi, T.Taniike, M.Terano,
Macromolecular Reaction Engineering, 7, 668-673, 2013.
Development of a Hetero-Bimetallic Phillips-Type Catalyst for Ethylene Polymerization
Y.Fukuyama, T.Kawai, S.Kuroda, M.Toyonaga, T.Taniike, M.Terano,
J. Therm. Anal. Calorim., 113, 1511-1519, 2013.
The effect of the addition of polypropylene grafted SiO2 nanoparticle on the crystallization behavior of isotactic polypropylene
P.Chammingkwan, V.Thang, M.Terano, T.Taniike,
Topics in Catalysis, 57, 91-97, 2014.
MgO/MgCl2/TiCl4 Core-Shell Catalyst for Establishing Structure-Performance Relationship in Ziegler-Natta Olefin Polymerization
T.Taniike, M.Terano,
Advances in Polymer Science, 257, 81-97, 2013.
The use of donors to increase the isotacticity of polypropylene
片田 一喜, 豊永 匡仁, 後藤 啓介, 小林 史紘, 千葉 響, 谷池 俊明, 寺野 稔,
高分子論文集, 70, 693-696, 2013.
ポリプロピレン系材料の劣化と安定化における高次構造の役割
K.Miyazaki, M.Hamadate, M.Terano, H.Nakatani
Applied Polymer SCIENCE, 2013, 915-922.
Syndiotactic Polypropylene / Microfibrous Cellulose Composites: Effect of Filler Size on Tensile Properties
K.Miyazaki, Y.Takahashi, M.Terano, H.Nakatani
Polym.Bull. , 2013, 1383-1395.
Additive effects of tripalmitin on morphologies and tensile properties of polybutene-1 and its composite with micro fibrous cellulose
S.Dwivedi, S.S.Gujral, T.Taniike, M.Terano
Pure Appl.Chem, 2013, 533-541.
Chemical modification of silica support to improve the branching ability of Phillips catalyst
2012
T.Taniike, M.Terano,
Journal of Catalysis, 2012, 293, 39-50.
Coadsorption Model for First-Principle Description of Roles of Donors in Heterogeneous Ziegler-Natta Propylene Polymerization
T.Taniike, P.Chammingkwan, V.Q.Thang, T.Funako, M.Terano,
Applied Catalysis: A General, 2012, 437-438, 24-27.
Validation of BET Specific Surface Area for Heterogeneous Ziegler-Natta Catalysts based on αS-Plot
T.Taniike, P.Chammingkwan, M.Terano,
Catalysis Communications, 2012, 27, 13-16.
Structure-Performance Relationship in Ziegler-Natta Olefin Polymerization with Novel Core-Shell MgO/MgCl2/TiCl4 Catalysts
K.Miyazaki, T.Arai, K.Shibata, M.Terano, H.Nakatani,
Polymer Degradation and Stability, 2012, 97, 2177-2184.
Study on biodegradation mechanism of novel oxo-biodegradable polypropylenes in an aqueous medium
T.Taniike, M.Terano,
Journal of Catalysis, 2012, 293, 39-50.
Coadsorption Model for First-Principle Description of Roles of Donors in Heterogeneous Ziegler-Natta Propylene Polymerization
T.Taniike, P.Chammingkwan, V.Q.Thang, T.Funako, M.Terano,
Applied Catalysis: A General, 2012, 437-438, 24-27.
Validation of BET Specific Surface Area for Heterogeneous Ziegler-Natta Catalysts based on αS-Plot
T.Taniike, P.Chammingkwan, M.Terano,
Catalysis Communications, 2012, 27, 13-16.
Structure-Performance Relationship in Ziegler-Natta Olefin Polymerization with Novel Core-Shell MgO/MgCl2/TiCl4 Catalysts
K.Miyazaki, T.Arai, K.Shibata, M.Terano, H.Nakatani,
Polymer Degradation and Stability, 2012, 97, 2177-2184.
Study on biodegradation mechanism of novel oxo-biodegradable polypropylenes in an aqueous medium
M. Umemori, T. Taniike, M. Terano,
Polymer Bulletin, 2012, 68, 1093-1108.
Influences of polypropylene grafted to SiO2 nanoparticles on the crystallization behavior and mechanical properties of polypropylene/SiO2 nanocomposites
T. Taniike, M. Umemori, F. Kobayashi, M. Terano,
Macromolecular Symposia, 2012.
Critical Role of Spherulite Structure on Behavior of Stabilizers in Polypropylene Stabilization
T. Taniike, S. Takahashi, T. Wada, K. Tonosaki, S. Dwivedi, M. Terano,
Macromolecular Symposia, 2012.
Model Catalysts for Clarification of Active Site-Polymer Relationship in Heterogeneous Olefin Polymerization
T. Taniike, S. Sano, M. Ikeya, V. Q. Thang, M. Terano,
Macromolecular Reaction Engineering, 2012.
Development of Large-Scale Stopped-Flow System for Heterogeneous Olefin Polymerization Kinetics
T. Taniike, M. Umemori, H. Chiba, K. Takeuchi, M. Terano,
Journal of Materials Life Society, 2012.
Critical Role of Interfacial Structures in Degradation and Stabilization of Polypropylene/SiO2 Composites
2011
H. Nakatani, K. Iwakura, K. Miyazaki, N. Okazaki, M. Terano,
J. Appl. Polym. Sci., 2011, 119, 1732-1741.
Effect of Chemical Structure of Silane Coupling Agent on Interface Adhesion Properties of
Syndiotactic Polypropylene/Cellulose Composite
T. Taniike, V. Q. Thang, N. T. Binh, Y. Hiraoka, T. Uozumi, M. Terano,
Macromolecular Chemistry and Physics , 2011, 212, 723-729.
Initial Particle Morphology Development in Ziegler-Natta Propylene Polymerization Tracked with Stopped-Flow Technique
K. Tonosaki, T. Taniike, M. Terano,
Macromolecular Reaction Engineering, 2011, 5, 332-339.
Comprehensive Investigation of Catalyst Structure and Polymerization Conditions for Chain Branching in Ethylene Polymerization with Phillips-Type Catalysts
K. Tonosaki, T. Taniike, M. Terano,
Journal of Molecular Catalysis A: Chemical, 2011, 340, 33-38.
Origin of Broad Molecular Weight Distribution of Polyethylene Produced by Phillips-type Silica-Supported Chromium Catalyst
T. Taniike, B. T. Nguyen, S. Takahashi, T. Q. Vu, M. Ikeya, M. Terano,
Journal of Polymer Science Part A: Polymer Chemistry, 2011, 49, 4005-4012.
Kinetic elucidation of comonomer-induced chemical and physical activation in heterogeneous ziegler-natta propylene polymerization
外崎 究, 谷池 俊明, 寺野 稔,
高分子論文集, 2011, 68-5,326-331.
Phillips 触媒を用いたエチレン重合における分子量分布および分岐構造の制御因子
平岡 優一, 谷池 俊明, 草野 正浩, 生駒 嘉晴, 寺野 稔,
高分子論文集, 2011, 68-7, 473-478.
工業用MgCl2担持型Ziegler-Natta触媒におけるTi種の粒子内分布と触媒特性との相関
高橋 彰吾, 和田 透, 谷池 俊明, 寺野 稔,
高分子論文集, 2011, 68-7,479-483.
TiCl3/MgCl2モデル触媒系におけるTi種の分散状態の制御と各種重合挙動への影響
N. Senso, P. Praserthdam, B. Jongsomjit, T. Taniike, M. Terano,
Polymer Bulletin, 2011, 67, 1979-1989.
Effects of Ti oxidation state on ethylene, 1-hexene comonomer polymerization by MgCl2-supported Ziegler–Natta catalysts
2010
W. Xia, B. Liu, Y. W. Fang, T. Fujitani, T. Taniike, M. Terano,
Appl. Catal. A: Gen., 2010, 389, 186-194.
Multinuclear solid-state NMR study of the coordinative nature of alkylaluminum cocatalyst on
Phillips CrOx/SiO2 catalyst
T. Taniike, S. Takahashi, T. Wada, I. Kouzai, M. Terano,
Macromol. Res., 2010, 18, 839-844.
Effects of molecular dispersion state of surface Ti species on ethylene-propylene copolymerization with
TiCl3-based Ziegler-Natta model catalyst
T. Taniike, T. Wada, I. Kouzai, S. Takahashi, M. Terano,
Macromol. Res., 2010, 18, 839-844.
Role of dispersion state of ti species in deactivation of MgCl2-supported Ziegler-Natta catalysts
Y. Hiraoka, S. Y. Kim, A. Dashti, T. Taniike, M. Terano,
Macromol. React. Eng., 2010, 4, 510-515.
Similarities and Differences of the Active Sites in Basic and Advanced MgCl2-Supported Ziegler-Natta
Propylene Polymerization Catalysts
R. Cheng, C. Xu, Z. Liu, Q. Dong, X. He, Y. Fang, M. Terano, Y. Fu, T. J. Pullukat, B. Liu,
J. Catal., 2010, 273, 103-115.
High-resolution spectroscopy (XPS, H-1 MAS solid-state NMR) and DFT investigations into Ti-modified
Phillips CrOx/SiO2 catalysts
A.T.M. Kamrul Hasan, Y. Fang, B. Liu, M. Terano,
Polymer, 2010, 51, 3627-3635.
Surface analytical approach to TiCl3-based Ziegler-Natta catalysts combined with microstructure analysis
of polymer
H. Nakatani, T. Ichizyu, H. Miura, M. Terano,
Polym. Int., 2010, 59, 463-471.
Novel modification of polybut-1-ene using auto-oxidation controlled by addition of limonene monomer
M. Umemori, T. Taniike, M. Terano,
Current Trends in Polymer Science , 2010, 14, 21-27.
Surface Polypropylene Modification of Silica Nanoparticles for the Improved Mechanical Properties of Polypropylene-based Nanocomposites
T. Taniike, M. Tada, R. Coquet, Y. Morikawa, T. Sasaki, Y. Iwasawa,
Top. Catal., 2010, 154, 118-126.
A Novel Mechanism for Spectator CO-Mediated Reaction with Unique cis-(NO)2 Dimer on a Co2+-dimer/γAl2O3(110) Model Catalyst: Density Functional Theory Calculations
2009
M. Suzuki, M. A. M. Ali, K. Okamoto, T. Taniike, M. Terano, M. Yamaguchi,
Adv. Polym. Tech., 2009, 28, 185-191.
Effect of Stereoregularity of Polypropylene on Flow Instability in Capillary Extrusion
A. Dashti, S. A. A. Ramazani, Y. Hiraoka, S. Y. Kim, T. Taniike, M. Terano,
Macromol. Symp., 2009, 285, 52-57.
Kinetic and Morphological Investigation on the Magnesium Ethoxide-Based Ziegler-Natta Catalyst
for Propylene Polymerization Using Typical External Donors
W. Xia, T. Taniike, M. Terano, T. Fujitani, B. Liu, J. B. P. Soares,
Macromol. Symp., 2009, 285, 74-80.
CRYSTAF Analysis of Polyethylene Synthesized with Phillips Catalyst
S. Y. Kim, Y. Hiraoka, T. Taniike, M. Terano,
Macromol. Symp., 2009, 285, 115-120.
External Donor Induced Direct Contact Effects on Mg(OC2H5)2-Based
Ziegler-Natta Catalysts for Propylene Polymerization
T. Taniike, M. Terano,
Macromol. Chem. Phys., 2009, 210, 2188-2193.
A Density Functional Study for Influences of Molecular Flexibility of Donors on Insertion Barrier
and Stereoselectivity of Ziegler-Natta Propylene Polymerization
Y. Hiraoka, A. Dashti, S. Y. Kim, T. Taniike, M. Terano,
Curr. Trends Polym. Sci., 2009, 18, 185-191.
Spatial Distribution of Active Ti Species on Morphology Controlled Mg(OEt)2-based Ziegler-Natta
catalyst
M. Suzuki, M. D. Amran, K. Okamoto, T. Taniike, M. Terano, M. Yamaguchi,
Adv. Polym. Tech., 2009, 18, 185-191.
Effect of Stereoregularity of Polypropylene on Flow Instability in Capillary Extrusion
V. Q. Thang, T. Taniike, M. Umemori, M. Ikeya, Y. Hiraoka, N. D. Nghia, M. Terano,
Macromol. React. Eng., 2009, 3, 467-472.
New Quenching Procedure for Preservation of Initial Polymer/Catalyst Particle Morphology
in Ziegler-Natta Olefin Polymerization
T. Wada, T. Taniike, I. Kouzai, S. Takahashi, M. Terano,
Macromol. Rapid Commun., 2009, 30, 887-891.
Propylene Polymerization Performance of Isolated and Aggregated Ti Species Studied Using a
Well-Designed TiCl3/MgCl2 Ziegler-Natta Model Catalyst
S. Y. Kim, Y. Hiraoka, T. Taniike, M. Terano,
Curr. Trends Polym. Sci., 2009, 12, 119-123.
Precise experimental approach to effects of an external donor on propylene polymerization with
Mg(OC2H5)2-based Ziegler-Natta catalysts
A. Dashti, A. Ramazani, Y. Hiraoka, S. Y. Kim, T. Taniike, M. Terano,
Polym. Int., 2009, 58, 40-45.
Kinetic and morphological study of a magnesium ethoxide-based Ziegler-Natta catalyst for
propylene polymerization
K. Miyazaki, K. Moriya, N. Okazaki, M. Terano, H. Nakatani,
J. Appl. Polym. Sci., 2009, 111, 1835-1841.
Cellulose/Polypropylene Composites: Influence of the Molecular Weight and Concentration of
Oxidatively Degraded and Maleated Polypropylene Compatibilizers on Tensile Behavior
W. Xia, K. Tonosaki, T. Taniike, M. Terano, T. Fujitani, B. Liu,
J. Appl. Polym. Sci., 2009, 111, 1869-1877.
Copolymerization of Ethylene and Cyclopentene with the Phillips CrOx/SiO2 Catalyst in the
Presence of an Aluminum Alkyl Cocatalyst
V.Q.Thang, T. Taniike, M. Umemori, M. Ikeya, Y. Hiraoka, M. Terano,
Journal of Materials Life Society. 2009, 22, 30-34.
Morphological Stability of the Initially Formed Polymer Particles with Stopped-Flow Propylene Polymerization
2008
K. Yoshida, T. Kawamura, M. Terano, K-H. Nitta,
J. Appl. Polym. Sci., 2008, 109, 211-217.
Effects of bulk morphology on the mechanical properties of melt-blended PP/PS blends
K. Yoshida, T. Kawamura, M. Terano, K-H. Nitta,
Nihon Reoroji Gakkaishi, 2008, 36, 29-34.
Additional effect of SEBS on dynamic mechanical properties in iPP/aPS blends
K. Tangjituabun, S. Y. Kim, Y. Hiraoka, T. Taniike, M. Terano, B. Jongsomjit, P. Praserthdam,
Chinese J. Polym. Sci., 2008, 26, 547-552.
Poisoning of Active Sites on Ziegler-Natta Catalyst for Propylene Polymerization
T. Taniike, M. Terano,
Macromol. Rapid Commun., 2008, 29, 1472-1476.
Reductive Formation of Isospecific Ti Dinuclear Species on a MgCl2 (110) Surface in Heterogeneous Ziegler-Natta Catalysts
K. Tangjituabun, S. Y. Kim, Y. Hiraoka, T. Taniike, M. Terano, B. Jongsomjit, P. Praserthdam,
Sci. Technol. Adv. Mater., 2008, 9, 024402 (4pp).
Effects of various poisoning compounds on the activity and stereospecificity of heterogeneous Ziegler-Natta catalyst
H. Nakatani, D. Kurniawan, T. Taniike, M. Terano,
Sci. Technol. Adv. Mater., 2008, 9, 024401 (5pp).
Degradation behavior of polymer blend of isotactic polypropylenes with and without unsaturated chain end group
K.-I. Sumino, T. Taniike, M. Terano, G. A. George,
Macromol. React. Eng., 2008, 2, 135-141.
Thermal and Photooxidative Degradation Behavior of Poly(propylene)/SiO2 Nanocomposites with Various Polymer Morphologies
2007
B. Liu, R. Cheng, Z. Liu, P. Qiu, S. Zhang, T. Taniike, M. Terano, K. Tashino, T. Fujita,
Macromol. Symp., 2007, 260, 42-48.
Experimental and Computational Approaches on the Isospecific Role of Monoester-Type Internal Electron Donor for TiCl4/MgCl2 Ziegler-Natta Catalysts
H. Nakatani, S. Suzuki, T. Tanaka, M. Terano,
Polym. Int., 2007, 56, 1147-1151.
Self-repairing property of polymer network with dangling chains
H. Nakatani, H. Matsuoka, S. Suzuki, T. Taniike, B. Liu, M. Terano,
Macromol. Symp., 2007, 257, 112-121.
Application of Fractionation Techniques to the Study of Olefin Polymerization Kinetics and Polymer Degradation
T. Taniike, M. Terano,
Macromol. Symp. 2007, 260, 98-106.
Density Functional Calculations for Electronic and Steric Effects of Ethyl Benzoate on Various Ti Species in MgCl2-Supported Ziegler-Natta Catalysts
I. Kouzai, T. Wada, T. Taniike, M. Terano,
Macromol. Symp. 2007, 260, 179-183.
Hydrogen Effects for Propylene Polymerization with Ultra Low TiCl3 Loading MgCl2-Supported Catalyst
K. Asuka, K. Sumino, T. Taniike, K. Nitta, M. Terano,
Materiaru Raifu Gakkaishi, 2007, 19, 128-131.
Effect of Silica on Sherulite Structure and Photo-oxidative Degradation Behavior in Polypropylene/Silica Nanocomposites
M. Yamaguchi, S. Ono, M. Terano,
Mat. Lett., 2007, 61, 1396-1399.
Self-repairing property of polymer network with dangling chains
T. Taniike, M. Terano,
Macromol. Rapid. Commun. 2007, 28, 1918-1922.
Coadsorption and Support-Mediated Interaction of Ti Species with Ethyl Benzoate in MgCl2-Supported Heterogeneous Ziegler-Natta Catalysts Studied by Density Functional Calculations
H. Nakatani, S. Suzuki, T. Tanaka, M. Terano,
Polym. Int., 2007, 56, 1147-1151.
Effect of unsaturated chain end-group on thermal oxidative behavior of polypropylene
I. Kouzai, B. Liu, T. Wada, M. Terano,
Macromol. React. Eng. 2007, 1, 160-164.
Effects of Hydrogen for Different Stereospecific Active Sites on Ultra Low TiCl3 Loading Supported Catalyst
2006
K. Nitta, K. Asuka, B. Liu, M. Terano,
Polymer 2006, 47, 6457-6463.
The Effect of the Addition of Silica Particles on Linear Spherulite Growth Rate of Isotactic Polypropylene and its Explanation by Lamellar Cluster Model
K. Asuka, B. Liu, M. Terano, K. Nitta,
Macromol. Rapid Commun. 2006, 27, 910-913.
Homogeneously Dispersed Polypropylene/SiO2 Nanocomposites with Unprecedented Transparency
W. Xia, B. Liu, Y. Fang, K. Hasebe, M. Terano,
J. Mol. Catal. A: Chem. 2006, 256, 301-308.
Unique Polymerization Kinetics Obtained from Simultaneous Interaction of Phillips Cr(VI)Ox/SiO2 Catalyst with Al-Alkyl Cocatalyst and Ethylene Monomer
Y. Fang, W. Xia, M. He, B. Liu, K. Hasebe, M. Terano,
J. Mol. Catal. A: Chem. 2006, 247, 240-247.
Novel SiO2-Supported Chromium Catalyst Bearing New Organo-Siloxane Ligand for Ethylene Polymerization
Q. Wang, Y. Lin, Z. Zhang, B. Liu, M. Terano,
J. Appl. Polym. Sci. 2006, 100, 1978-1982.
High Temperature Polymerization of Propylene Catalyzed by MgCl2-Supported Ziegler-Natta Catalysts with Various Cocatalysts
N. Manabe, Y. Yokota, H. Nakatani, S. Suzuki, B. Liu, M. Terano,
J. Appl. Polym. Sci. 2006, 100, 1831-1835.
Local Thermal Degradation Behavior of Heterophasic Polypropylene Copolymers
Y. Fang, B. Liu, M. Terano,
Kinet. Catal. 2006, 47, 295-302.
Various Activation Procedures of Phillips Catalyst for Ethylene Polymerization
B. Liu, Y. Fang, Wei Xia, M. Terano,
Kinet. Catal. 2006, 47, 234-240.
Theoretical Investigation of Novel Silsesquioxane-Supported Phillips Type Catalyst by Density Functional Theory (DFT) Method
B. Liu, W. Xia, M. Terano,
Stud. Surf. Sci. Catal. 2006, 161, 129-134.
Computational Approach on the Interaction between CrO3 and Ethylene as a Model for the Understanding of Phillips Catalyst
W. Xia, B. Liu, Y. Fang, D. Zhou, M. Terano,
Stud. Surf. Sci. Catal. 2006, 161, 225-228.
Plausible mechanism for the formation and transformation of active sites on novel Phillips type catalyst with new organo-siloxane ligand
A. Shiga, B. Liu, M. Terano,
Stud. Surf. Sci. Catal. 2006, 161, 219-224.
Theoretical Study on Active Site Formation of Olefin Metathesis and Olefin Polymerization in Phillips CrOx/SiO2 Catalyst by PIO Analysis
K. Asuka, I. Kouzai, B. Liu, M. Terano, K. Nitta,
Stud. Surf. Sci. Catal, 2006, 161, 237-240.
Effects of silica particles on the transparency of polypropylene based nanocomposites
K. Sumino, K. Asuka, B. Liu, M. Yamaguchi, M. Terano, T. Kawamura, K. Nitta,
Stud. Surf. Sci. Catal, 2006, 161, 229-232.
Influence of polymer morphology on photo-stability of polypropylene/SiO2 nanocomposites
H. Matsumura, M. Ishikawa, K. Kida, K. Maenaka, T. Kuno, K. Nitta, M. Terano, S. Minami,
Jpn. J. Appl. Phys. 2006, 45, 4413-4418.
Development of micro-assembling technology for fabrication of large size liquid crystal displays
中谷久之, 寺野稔,
日本ゴム協会誌 2006, 79, 440-442.
一次構造制御によるポリプロピレンの高安定化,
2005
K. Nitta, Y. W. Shin, H. Hashimoto, S. Tanimoto, M. Terano,
Polymer 2005, 46, 965-975.
Morphology and mechanical properties in the binary blends of isotactic polypropylene and novel propylene-co-olefin random copolymers with isotactic propylene sequence 1. Ethylene-propylene copolymers,
Q. Wang, N. Murayama, B. Liu, M. Terano,
Macromol. Chem. Phys. 2005, 206, 961-966.
Effects of Electron Donors on Active Sites Distribution of MgCl2-Supported Ziegler-Natta Catalysts Investigated by Multiple Active Sites Model
N. Manabe, Y. Yokota, H. Nakatani, S. Suzuki, B. Liu, M. Terano,
Polym. Bull. 2005, 54, 141-145.
Study of local oxidative degradation in polypropylene impact copolymer by energy dispersive X-ray system
B. Liu, N. Murayama, M. Terano,
Ind. Eng. Chem. Res. 2005, 44, 2382-2388.
Transformation of Polymerization Sites into Hydrogen Dissociation Sites on Propylene Polymerization Catalyst Induced by the Reaction with Al-Alkyl Cocatalyst
A.T.M. Kamrul Hasan, B. Liu, M. Terano,
Polym. Bull. 2005, 54, 225-236.
Effect of Various Preparation and Polymerization Procedures on the Isospecific Nature of TiCl3-Based Polypropylene Catalysts
Y. Fang, B. Liu, M. Terano,
Appl. Catal. A: General 2005, 279, 131-138.
Photo-stability of surface chromate species on Phillips CrOx/SiO2 catalysts isothermally calcined at various temperatures, probed by high resolution X-ray photoelectron spectroscopy
S. Suzuki, Y. Nakamura, A.T.M. Kamrul Hasan, B. Liu, M. Terano, H. Nakantani,
Polym. Bull. 2005, 54, 311-319.
Dependence of tacticity distribution in thermal oxidative degradation of polypropylene
S. Suzuki, B. Liu, M. Terano, N. Manabe, K. Kawamura, M. Ishikawa, H. Nakantani,
Polym. Bull. 2005, 55, 141-147.
Influence of primary structure on thermal oxidative degradation of polypropylene impact copolymer
B. Liu, P. Sindelar, Y. Fang, K. Hasebe, M. Terano,
J. Mol. Catal. A: Chem. 2005, 238, 142-150.
Correlation of oxidation states of surface chromium species with ethylene polymerization activity for Phillips CrOx/SiO2 catalysts modified by Al-alkyl cocatalyst
Y. Fang, B. Liu, K. Hasebe, M. Terano,
J. Polym. Sci. A: Polym. Chem. 2005, 43, 4632-4641.
Ethylene and 1-Hexene Copolymerization with CO-Prereduced Phillips CrOx/SiO2 Catalyst in the Presence of Al-Alkyl Cocatalyst
H. Nakatani, S. Suzuki, M. Tanaka, M. Terano,
Polymer 2005, 46, 12366-12371.
New kinetic aspects on the mechanism of thermal oxidative degradation of polypropylenes with various tacticities
中谷久之, 真鍋礼男, 川村健一, 石川正尚, 鈴木正太郎, 寺野稔,
マテリアルライフ学会誌 2005, 17, 146-149.
ポリプロピレンインパクトコポリマーにおける熱酸化劣化挙動と一次構造の関係
N. Manabe, K. Kawamura, M. Ishikawa, S. Suzuki, B. Liu, M. Terano, H. Nakatani,
Polymer Testing 2005, 24, 994-997.
Development of a novel potentiometric titration method for determination of polypropylene degradation
2004
Y. W. Shin, H. Hashiguchi, M. Terano, K. Nitta,
J. Appl.Polym. Sci. 2004, 92, 2949-2954.
Synthesis and Characterization of Propylene-a-Olefin Random Copolymers with Isotactic Propylene Sequence. II. Propylene?Hexene-1 Random Copolymer
真鍋礼男, 川村健一, 石川正尚, 中谷久之, 寺野稔,
マテリアルライフ学会誌 2004, 16, 59-63.
ポリプロピレンインパクトコポリマーの熱酸化劣化と過酸化物価
寺野稔, 飛田悦男, 瀬川修, 寒河江竹弘, 扇澤雅明,
未来材料 2004, 4, 28-35.
ポリオレフィンにおけるさらなる省エネルギープロセスへの取り組み
B. Liu, K. Fukuda, H. Nakatani, I. Nishiyama, M. Yamahiro M. Terano,
J. Mol. Catal. A: Chem. 2004, 219, 363-370.
27Al MAS solid state NMR study on coordinative nature of alkyl-Al cocatalysts on a novel SiO2-supported Ziegler?Natta catalyst for controlled multiplicity of molecular weight distribution
B. Liu, Y. Fang, M. Terano,
J. Mol. Catal. A: Chem. 2004 219 165-173.
High resolution X-Ray photoelectron spectroscopic analysis of transformation of surface chromium species on Phillips CrOx/SiO2 catalysts isothermally calcined at various temperatures
N. Murayama, B. Liu, H. Nakatani, M. Terano,
Polym. Int. 2004 53 723-727.
Plausible guard effect on the active sites of heterogeneous Ziegler-Natta catalyst by coordinating monomers and growing polymer chains in the initial stage of propene polymerization
B. Liu, Y. Fang, H. Nakatani, M. Terano,
Macromol. Symp. 2004, 213, 37-46
Surface Physico-Chemical State of CO-Prereduced Phillips CrOx/SiO2 Catalyst and Unique Polymerization Behavior in the Presence of Al-Alkyl Cocatalyst
B. Liu, T. Nitta, H. Nakatani, M. Terano,
Macromol. Symp. 2004, 213, 7-18.
Precise Arguments on the Distribution of Stereospecific Active Sites on MgCl2-Supported Ziegler-Natta Catalysts
M. Terano, B. Liu, H. Nakatani,
Macromol. Symp. 2004, 214, 299-306.
New Approaches for the Development of Highly Stable Polypropylene
飛鳥一雄， 劉柏平， 寺野稔， 新田晃平，
成形加工 2004, 16, 617-622.
ポリプロピレン/シリカナノコンポジット急冷固化フィルムにおける構造と力学的性質
B. Liu, K. Asuka, M. Terano, K. Nitta,
Current Achievements on Heterogeneous Olefin Polymerization Catalysts 2004, 119-126.
Effect of Particle Size on Mechanical Properties of Polypropylene/SiO2 Nanocomposites
B. Liu, M. Terano,
Current Achievements on Heterogeneous Olefin Polymerization Catalysts 2004, 77-84.
Theoretical Approach to the Activation Mechanism of Phillips CrOx/SiO2 Catalyst by Ethylene Monomer Using Paired Interacting Orbitals (PIO) Method
B. Liu, N. Murayama, Y. Fang, H. Nakatani, M. Terano,
Current Achievements on Heterogeneous Olefin Polymerization Catalysts 2004, 240-248.
Investigation on the Active Sites Transformation in Heterogeneous Olefin Polymerization Catalysis
中谷久之，劉柏平，寺野稔，
触媒，2004, 46, 622-627.
Ziegler-NattaおよびPhillips触媒における活性点の機能転換
2003
Y. W. Shin, H. Nakatani, T. Uozumi, B. Liu, T. Sano, K. Nitta, M. Terano,
Polym. Int. 2003, 52, 29-34.
Stepwise polymerization of polypropylene and ethylene with Cr(acac)3/MgCl2-EB/DEAC catalyst system
B. Liu, T. Nitta, H. Nakatani, M. Terano,
Macromol. Chem. Phys. 2003, 204, 395-402.
Stereospecific Nature of Active Sites on TiCl4/MgCl2 Ziegler-Natta Catalyst in the Presence of an Internal Electron Donor
I. Nishiyama, B. Liu, H. Matsuoka, H. Nakatani, M. Terano,
Macromol. Symp. 2003, 193, 71-80.
Kinetic Evaluation of Various Isospecific Active Sites on MgCl2-supported Ziegler Catalyst
T. Higuchi, B. Liu, H. Nakatani, N. Otsuka, M. Terano,
Appl. Surf. Sci. 2003,214, 272-277.
High Resolution Transmission Electron Microscope Observation of a-TiCl3
B. Liu, H. Nakatani, M. Terano,
J. Mol. Catal. A: Chem. 2003, 201, 189-197.
Mechanistic Implications of the Unprecedented Transformations of Ethene into Propene and Butene over Phillips CrOx/SiO2 Catalyst During Induction Period.
畑中知幸, 寺野稔,
高分子の寿命予測と長寿命化技術 応用編-3, 第4章 第3節
高分子劣化（酸化）機構解析へのアプローチ
中谷久之, 劉柏平, 寺野稔,
未来材料 2003, 3, 34.
ポリオレフィン用高機能光安定剤の開発
B. G. S. Goss, H. Nakatani, G. A. George, M. Terano,
Polym. Degrad. Stab. 2003, 82, 119-126.
Catalyst residue effects on the heterogeneous oxidation of polypropylene
中谷久之, 市来智仁, M. S. Alam, 劉柏平, 飛田悦男, 寺野稔,
マテリアルライフ学会誌 2003, 15, 137-142.
コモノマー導入によるイソタクチックポリプロピレンの熱・光安定性の改善
K. Fukuda, B. Liu, H. Nakatani, I. Nishiyama, M. Yamahiro, M. Terano,
Catal. Commun. 2003, 4, 657-662.
Significant variation of molecular weight distribution (MWD) of polyethylene induced by different alkyl-Al co-catalysts using a novel surface functionalized SiO2-supported Ziegler-Natta catalyst
2002
H. Kono, H. Mori, M. Terano, H. Nakatani, I. Nishiyama,
J. Appl. Polym. Sci. 2002, 83, 2976.
Influence of electron donor on the initial stage of cyclopolymerization of 1,5-hexadiene with MgCl2-supported Ziegler catalysts analyzed by temperature rising elution fractionation
T. Nitta, B. Liu, H. Nakatani, M. Terano,
J. Mol. Catal. A: Chem. 2002, 180, 25-34.
Formation, deactivation and transformation of stereospecific active sites on TiCl4/Dibutylphthalate/Mg(OEt)2 catalyst induced by short time reaction with Al-alkyl cocatalyst
H. Matsuoka, B. Liu, H. Nakatani, I. Nishiyama, M. Terano,
Polym. Int. 2002, 51, 781-784.
Active sites deterioration of MgCl2-supported catalyst induced by the electron donor extraction by alkylaluminium
H. Sano, H. Miyaoka, T. Kuze, H. Mori, G. Mizutani, N. Otsuka, M. Terano,
Surf. Sci. 2002, 70, 502-503.
Raman spectra of Magnesium chloride thin films
B. Liu, T. Nitta, H. Nakatani, M. Terano,
Macromol. Chem. Phys. 2002, 203, 2412-2421.
Specific Roles of Al-Alkyl Cocatalyst in the Origin of Isospecificity of Active Sites on Donor-Free TiCl4/MgCl2 Ziegler-Natta Catalyst
M. S. Alam, H. Nakatani, B. G. S. Goss, T. Ichiki, B. Liu, M. Terano,
J. Appl. Polym. Sci. 2002, 86, 1863-1867
Improvement of the Photostability of Isotactic Polypropylene by the Incorporation of Ethylene
B. Liu, H. Nakatani, M. Terano,
J. Mol. Catal. A: Chem. 2002, 184, 387.
New Aspects of the Induction Period of Ethene Polymerization using Phillips CrOx/SiO2 Catalyst Probed by XPS, TPD and EPMA
G. Mizutani, H. Miyaoka, H. Sano, H. Mori, N. Otsuka, M. Terano,
Future Technology for Polyolefin and Olefin Polymerization Catalysis 2002, 55-60
Vibrational spectra of titanium and magnesium chlorides
P. Sindelar, B. Liu, M. Terano,
Future Technology for Polyolefin and Olefin Polymerization Catalysis 2002, 200-209.
Ethylene polymerization tests and XPS measurements of the CrOx/SiO2 catalyst modified by Et3Al
M. S. Alam, T. Ichiki, B. Liu, H. Nakatani, K. Nitta, M. Terano,
Future Technology for Polyolefin and Olefin Polymerization Catalysis 2002, 249-254.
Effect of primary structure on photo-oxidative stability of polypropylene
I. Nishiyama, K. Fukuda, M. Yamahiro, B. Liu, H. Nakatani, M. Terano,
Future Technology for Polyolefin and Olefin Polymerization Catalysis 2002, 345-350.
Preparation of surface alkylated silica supported catalysts for ethylene polymerization
H. Matsuoka, B. Liu, H. Nakatani, I. Nishiyama, M. Terano,
Future Technology for Polyolefin and Olefin Polymerization Catalysis 2002, 365-371
Investigation of effects and roles of internal and external donors on the isospecificity distribution of the active sites of a Ziegler catalyst by temperature rising elution fraction analysis
B. Liu, H. Nakatani, M. Terano,
Future Technology for Polyolefin and Olefin Polymerization Catalysis 2002, 409-414
Probing the induction period of Phillips CrOx/SiO2 catalyst through combined surface analytical methods
Y. W. Shin, H. Nakatani, T. Uozumi, B. Liu, T. Sano, K. Nitta, M. Terano,
Future Technology for Polyolefin and Olefin Polymerization Catalysis 2002, 421-424
Stability of growing polymer chain on the Cr(acac)3/MgCl2-ethylbenzoate/AlEt2Cl catalyst system
M. S. Alam, H. Nakatani, B. Liu, M. Terano,
Recent Res. Devel. Macromol. 2002, 6, 213-227.
Effect of ethylene incorporation into isotactic polypropylene on photo and thermo-oxidative degradation
M. S. Alam, T. Ichiki, B. Liu, H. Nakatani, M. Terano,
Recent Res. Devel. Polymer Science 2002, 6, 19-25.
Study of the photo-oxidative degradation behavior of ethylene-propylene random copolymer
松岡仁志, 西山伊佐, 中谷久之, 劉柏平, 寺野稔,
高分子論文集 2002, 59, 402.
昇温溶離分別法を用いたMgCl2担持型Ziegler触媒におけるイソ立体特異的活性点の特性分布解析
2001
B. Liu, H. Matsuoka, M. Terano,
Macromol. Rapid Commun. 2001, 22, 1.
Stopped-flow techniques in Ziegler catalysis
H. Matsuoka, B. Liu, H. Nakatani, M. Terano,
Macromol. Rapid Commun. 2001, 22, 326.
Variation in the isospecific active sites of internal donor-free MgCl2-supported Ziegler catalysts: effect of external electron donors
B. Liu, H. Matsuoka, M. Terano,
Macromol. Symp. 2001, 165, 3.
Kinetic investigation of propene polymerization with stopped-flow method
H. Kono, T. Ichiki, H. Mori, H. Nakatani, M. Terano,
Polym. Int. 2001, 50, 568.
Basic characterization of polypropene-block-poly(methylene-1,3-cyclopentane-co-propene) synthesized from propene and 1,5-hexadiene with modified stopped-flow method
H. Kono, H. Mori, M. Terano,
Macromol. Chem. Phys. 2001, 202, 1319.
Novel olefin block copolymer, polypropene-block-poly(methylene-1,3-cyclopentane-co-propene), synthesized from propene and 1,5-hexadiene by a modified stopped-flow method
H. Miyaoka, T. Kuze, H. Sano, H. Mori, G. Mizutani, S. Ushioda, N. Otsuka, M. Terano,
Int. J. Modern Phys. B 2001, 15, 3865.
Raman spectrum of Titanium Di-, Tri-, and Tetra-Chlorides
B. Liu, M. Terano,
J. Mol. Catal. A: Chem. 2001, 172, 227.
Investigation of the physico-chemical state and aggregation mechanism of surface Cr species on a Phllips CrOx/SiO2 catalyst by XPS and EPMA
Y. W. Shin, T. Uozumi, M. Terano, K. Nitta,
Polymer 2001, 42, 9611.
Synthesis and characterization of ethylene-propylene random copolymers with isotactic propylene sequence
K. Hasebe, M. Terano,
Micro-Kinetics and Dynamics of Individual Active Sites in Catalytic Reactions 2001, 74-80.
X-Ray Photoelectron Spectroscopy Analysis of Interaction between Titanium Species and Internal Donor on the Surface of MgCl2-Supported Ziegler-Natta Catalysts
B. Liu, M. Terano.
Micro-Kinetics and Dynamics of Individual Active Sites in Catalytic Reactions 2001, 81-87
Distribution State of Surface Chromium Species on Phillips Catalysts Treated in Various Atmospheres
H. Matsuoka, B. Liu, H. Nakatani, M. Terano,
Micro-Kinetics and Dynamics of Individual Active Sites in Catalytic Reactions 2001, 88-93.
Transformation of Stereospecific Active Sites on Internal Donor-free MgCl2-Supported Ziegler Catalyst by Addition of External Electron Donor
G. Mizutani, H. Miyaoka, H. Sano, H. Mori, S. Ushioda, N. Otsuka, M. Terano,
Micro-Kinetics and Dynamics of Individual Active Sites in Catalytic Reactions 2001, 94-104.
Raman Analysis of a-TiCl3 , a Basic Componetnt of the Ziegler-Natta Catalyst
T. Sakurai, M. Uno, E. Nakamura, T. Horigome, H. Kita, K. Higashimine, T. Nitta, H. Mori, M.Terano,
Micro-Kinetics and Dynamics of Individual Active Sites in Catalytic Reactions 2001, 105-108.
Design and Construction of a New Time-of-Flight Mass Spectrometer for Temporal Analysis of the Characteristics of Active Sites of Ziegler Catalyst
B. Liu, T. Shimizu, M. Terano,
Organometallic Catalyts and Olefin Polymerization 2001, 206-216.
Surface Analytical Approaches for the Phillips Catalyst by EPMA and XPS
H. Kono, M. Tomisaka, H. Matsuoka, B. Liu, M. Terano,
Organometallic Catalyts and Olefin Polymerization 2001, 196-205.
Basic Approaches for the Design of Active Sites on the Traditional Ziegler Catalysts
B. Liu, P. Sindelar, M. Terano,
Advances on Organometallic Catalysts and Olefin Polymerization in China and Germany 2001, 194-199.
Plausible Structure of Active Chromium Species on the Phillips Catalyst in the Presence of Cocatalyst
M. Terano, M. Yamahiro, H. Kono, H. Nakatani, B. Liu,
Abstr. Pap. Am. Chem. Soc. 2001, 221, 381.
Synthesis of novel olefin block copolymer by stopped-flow polymerization method and its application for investigation of stereospecific active sites on MgCl2-supported Ziegler catalyst
中谷久之、寺野稔,
界面ハンドブック 2001, 638-645.
中谷久之, 松岡仁志, 寺野稔,
新世代高機能ポリマーの創製と最新触媒技術 2001, 3-20.
中谷久之, 寺野稔,
月刊 高分子加工2001, 50, 8-14.
ヒンダードアミン末端修飾ポリエチレンの合成とその酸化防止効果
中谷久之, 山廣幹夫, 劉柏平, 寺野稔,
Journal of Materials Life Society 2001, 13, 175.
オレフィン重合触媒における熟成
中谷久之, 開発信和, 劉柏平, 寺野稔, 飛田悦男,
Journal of Materials Life Society 2001, 13, 185.
新規光安定化剤ヒンダードアミン末端修飾型ポリエチレンの合成とその光安定化能の評価
2000
H. Miyaoka, T. Kuze, H. Sano, H. Mori, G. Mizutani, S. Ushioda, N. Otsuka, M. Terano,
J. Luminescence 2000, 87-89, 709.
Raman spectrum of ball-milled a-TiCl3
H. Mori, H. Kono, M. Terano,
Macromol. Chem. Phys. 2000, 201, 543.
Microstructural heterogeneities of the cyclopolymer of 1,5-hexadiene obtained by stopped-flow and conventional methods: correlation to plural active sites for polypropene on MgCl2-supported Ziegler catalyst
H. Mori, M. Yamahiro, M. Terano, M. Takahashi, T. Matsukawa,
Macromol. Chem. Phys. 2000, 201, 289.
Lifetime of growing polymer chain in stopped-flow propene polymerization using pre-treated Ziegler catalysts
H. Mori, H. Kono, M. Terano, A. Nosov, V. A. Zakharov,
J. Mol. Catal. A: Chem. 2000, 164, 235.
In-situ multinuclear solid state NMR spectroscopy under continuous-flow conditions for investigations of Ziegler-Natta catalyzed propene polymerization
H. Mori, T. Higuchi, N. Otsuka, M. Terano,
Macromol. Chem. Phys. 2000, 201, 2789.
High resolution transmission electron microscope observation of industrial high performance Ziegler catalysts
H. Nakatani, T. Hatanaka, K. Nitta, M. Terano,
Res. Adv. in Macromolecules 2000, 1, 17.
Thermo- and photo-oxidation of polypropylenes with different tacticities
H. Mori, M. Terano,
Progress and Development of Catalytic Olefin Polymerization 2000, 65-74.
Surface Characterization of Ziegler-Natta Catalysts : XPS, SAM, HRTEM, and in-situ Solid State NMR Studies
I. Cejpek, J. Kratochvila, J. Mejzlik, M. Terano,
Progress and Development of Catalytic Olefin Polymerization 2000, 272-279.
Modeling of Commercial Gas Phase Polymerization in Bench-Scale Reactor : Propylene Homo- and Copolymerization with Ethylene
H. Nakatani, T. Hatanaka, K. Nitta, M. Terano,
Progress and Development of Catalytic Olefin Polymerization 2000, 280-287.
Thermo- and Photo-Oxidative Degradation of Polypropylenes with Various Primary Structures
M. Terano, H. Matsuoka, B. Liu,
Polymer Preprints (ACS), 2000, 41, 1914-1915.
Variation of Isospecific Active Sites on MgCl2-supported Ziegler Catalysts
寺野稔, 中谷久之, 新田晃平,
技術予測シリーズ・21世紀に期待される技術～その将来展望第5巻, 日本ビジネスレポート
高安定性ポリオレフィン製造技術の将来展望
寺野稔, 中谷久之, 塩野毅,
技術, 第2編 第2章
オレフィン系, スチレン系樹脂の高機能化／改質
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