{"id":11,"date":"2023-03-23T15:07:37","date_gmt":"2023-03-23T06:07:37","guid":{"rendered":"https:\/\/www.jaist.ac.jp\/nmcenter\/labs\/gotoh-www\/?page_id=11"},"modified":"2026-03-26T12:49:23","modified_gmt":"2026-03-26T03:49:23","slug":"research","status":"publish","type":"page","link":"https:\/\/www.jaist.ac.jp\/nmcenter\/labs\/gotoh-www\/research","title":{"rendered":"\u7814\u7a76\u5185\u5bb9"},"content":{"rendered":"\n

\u7814\u7a76\u5185\u5bb9<\/h2>\n\n\n\n
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\"\"<\/figure>\n<\/div>\n<\/div>\n\n\n\n

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\"\"<\/figure><\/div>\n\n\n

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1)<\/sup> K.Gotoh et al., Carbon<\/em> (2014).  2)<\/sup> K.Gotoh et al., J. Mater Chem. A <\/em>(2020).<\/p>\n\n\n\n

\uff08\uff12\uff09\u5168\u56fa\u4f53\u96fb\u6c60\u306e\u30aa\u30da\u30e9\u30f3\u30c9NMR\u8a08\u6e2c\u5b9f\u73fe\u3068\u62e1\u6563\u30e1\u30ab\u30cb\u30ba\u30e0\u89e3\u660e<\/strong><\/p>\n\n\n\n

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\"\"<\/figure>\n\n\n\n

\u65b0\u898fNa\u96fb\u6c60\u8ca0\u6975\u306e\u5145\u653e\u96fb\u30d7\u30ed\u30d5\u30a1\u30a4\u30eb\u3068Na\u5438\u8535\u30e2\u30c7\u30eb3)<\/sup><\/p>\n\n\n\n

3)<\/sup> K.Gotoh et al., Carbon<\/em> Trends<\/em> (2024).<\/p>\n\n\n\n

\u25c6\u65b0\u898f\u5c64\u9593\u5316\u5408\u7269\u306e\u5408\u6210\u3068\u8868\u9762\u72b6\u614b\u30fb\u30c0\u30a4\u30ca\u30df\u30af\u30b9\u306e\u89b3\u6e2c<\/strong><\/h3>\n\n\n\n

\u9ed2\u925b\u3084\u7121\u6a5f\u5c64\u72b6\u5316\u5408\u7269\u306e\u5c64\u9593\u306f2\u6b21\u5143\u7a7a\u9593\u3067\u3042\u308b\u3053\u3068\u304b\u3089\u3001\u305d\u306e\u7a7a\u9593\u306b\u5c0e\u5165\u3055\u308c\u305f\u5206\u5b50\u3084\u30a4\u30aa\u30f3\u306f\u30d0\u30eb\u30af\uff08\u901a\u5e38\u306e3\u6b21\u5143\u306b\u7269\u8cea\u304c\u96c6\u5408\u3057\u305f\u72b6\u614b\uff09\u3068\u306f\u7570\u306a\u308b\u7269\u6027\u3092\u767a\u73fe\u3057\u307e\u3059\u3002\u65b0\u898f\u9ed2\u925b\u7cfb\u5c64\u9593\u5316\u5408\u7269\u306e\u5408\u6210\u3068\u69cb\u9020\u89e3\u6790\u3001\u305d\u308c\u3089\u306e\u96fb\u6c60\u96fb\u6975\u3078\u306e\u5fdc\u7528\u304a\u3088\u3073\u96fb\u5b50\u30fb\u30d7\u30ed\u30c8\u30f3\u4f1d\u5c0e\u306b\u3064\u3044\u3066\u306e\u7814\u7a76\u3092\u884c\u3063\u3066\u3044\u307e\u3059\u3002<\/p>\n\n\n

\n
\"\"<\/figure><\/div>\n\n\n

<\/p>\n\n\n\n

Diglyme\u6eb6\u5a92\u548c\u3055\u308c\u305f\u30ca\u30c8\u30ea\u30a6\u30e0\u30a4\u30aa\u30f3\u306e\u9ed2\u925b\u5c64\u9593\u3067\u306e\u69cb\u9020\u304a\u3088\u3073\u5206\u5b50\u904b\u52d5\u30e2\u30c7\u30eb4)<\/sup><\/p>\n\n\n\n

4)<\/sup> K.Gotoh et al., J. Phys. Chem C<\/em> (2016).<\/p>\n\n\n\n

\u25c6\u56fa\u4f53NMR\u306b\u3088\u308b\u70ad\u7d20\u306e\u8868\u9762\u89e3\u6790\u6cd5\u306e\u958b\u767a<\/strong><\/h3>\n\n\n\n

\u70ad\u7d20\u6750\u6599\u306e\u6027\u8cea\u306f\u3001\u8868\u9762\u5b98\u80fd\u57fa\u306e\u7a2e\u985e\uff08\u6c34\u9178\u57fa\u3084\u30ab\u30eb\u30dc\u30ad\u30b7\u30eb\u57fa\u3001\u30a8\u30dd\u30ad\u30b7\u57fa\u3001\u30e1\u30c1\u30eb\u57fa\u7b49\uff09\u3084\u7d50\u5408\u91cf\u306b\u3088\u308a\u3001\u5927\u304d\u304f\u5909\u308f\u308b\u3053\u3068\u304c\u77e5\u3089\u308c\u3066\u3044\u307e\u3059\u3002\u3053\u306e\u8868\u9762\u5b98\u80fd\u57fa\u306e\u72b6\u614b\u3092\u628a\u63e1\u3057\u3001\u5236\u5fa1\u3059\u308b\u3053\u3068\u304c\u6750\u6599\u958b\u767a\u306b\u304a\u3044\u3066\u91cd\u8981\u306b\u306a\u308a\u307e\u3059\u3002\u56fa\u4f53NMR\u306f\u5b98\u80fd\u57fa\u3092\u7cbe\u5ea6\u3088\u304f\u691c\u51fa\u3067\u304d\u308b\u3082\u306e\u306e\u3001\u5f93\u6765\u306e\u65b9\u6cd5\uff0813<\/sup>C direct excitation, 1<\/sup>H-13<\/sup>C CPMAS\uff09\u3067\u306f\u691c\u51fa\u611f\u5ea6\u304c\u4f4e\u3044\u3068\u3044\u3046\u554f\u984c\u304c\u3042\u308a\u307e\u3057\u305f\u3002\u5f53\u7814\u7a76\u5ba4\u3067\u306f\u3001\u4ed6\u5927\u5b66\u3068\u306e\u5171\u540c\u7814\u7a76\u306b\u3088\u308a\u52d5\u7684\u6838\u504f\u6975(DNP) NMR\u3092\u7528\u3044\u305f\u9ad8\u7cbe\u5ea6\u304b\u3064\u9ad8\u611f\u5ea6\u306a\u70ad\u7d20\u6750\u6599\u306e\u8868\u9762\u5206\u6790\u6cd5\u306e\u958b\u767a\u3092\u9032\u3081\u3066\u3044\u307e\u3059\u3002<\/p>\n\n\n

\n
\"\"<\/figure><\/div>\n\n\n

DNP – NMR\u306b\u3088\u308b\u70ad\u7d20\u8868\u9762\u5b98\u80fd\u57fa\u306e\u89b3\u6e2c 5)<\/sup><\/p>\n\n\n\n

5)<\/sup> H. Ando, K. Suzuki, H. Kaji, T. Kambe, Y. Nishina, C. Nakano, K. Gotoh, Carbon (2023).<\/p>\n\n\n\n

\u6240\u6709\u30fb\u7ba1\u7406\u88c5\u7f6e     <\/h2>\n\n\n\n
    \n
  • Bruker AVANCE \u2162 500MHz-NMR\uff08\u56fa\u4f53\u9ad8\u5206\u89e3\u80fd\uff081<\/sup>H,13<\/sup>C, Li, Na, B, P\u7b49\uff09\u6e2c\u5b9a\u5bfe\u5fdc\uff09<\/li>\n\n\n\n
  • Bruker AVANCE Neo 400MHz-NMR \uff08\u56fa\u4f53\u5c02\u7528\u6a5f\uff09<\/li>\n\n\n\n
  • NMR\u30aa\u30da\u30e9\u30f3\u30c9\u8a08\u6e2c\u7528\u5145\u653e\u96fb\u5bfe\u5fdc\u7279\u6b8a\u30d7\u30ed\u30fc\u30d6\u304a\u3088\u3073\u5c02\u7528\u5145\u653e\u96fb\u30b7\u30b9\u30c6\u30e0 <\/li>\n\n\n\n
  • NMR\u30fb\u56fa\u4f53\u7528\u62e1\u6563\u6e2c\u5b9a\u30b7\u30b9\u30c6\u30e0\uff08\u78c1\u5834\u52fe\u914d\u5f37\u5ea6\uff1a28T\/m\uff08\u5e02\u8ca9\u54c1\u4e16\u754c\u6700\u9ad8\uff09\uff09<\/li>\n\n\n\n
  • \u793a\u5dee\u8d70\u67fb\u71b1\u91cf\u8a08\uff08DSC\uff09<\/li>\n\n\n\n
  • \u71b1\u91cd\u91cf\u5206\u6790\u88c5\u7f6e\uff08TGA\uff09<\/li>\n\n\n\n
  • \u96fb\u6c17\u5316\u5b66\u8a08\u6e2c\u88c5\u7f6e\uff08CV,LSV\u6e2c\u5b9a\u7b49\uff09<\/li>\n\n\n\n
  • \u5145\u653e\u96fb\u8a66\u9a13\u88c5\u7f6e\uff08\u30b3\u30a4\u30f3\u30bb\u30eb\u7528\uff0c\u7279\u6b8a\u30bb\u30eb\u7528\uff0cNMR\u5b9f\u9a13\u7528\u542b\u3080\uff09<\/li>\n\n\n\n
  • \u30a4\u30f3\u30d4\u30fc\u30c0\u30f3\u30b9\u30a2\u30ca\u30e9\u30a4\u30b6\u30fc\uff08\uff5e10MHz\u5bfe\u5fdc\uff09<\/li>\n\n\n\n
  • \u96fb\u6c60\u4f5c\u88fd\u8a2d\u5099\uff08\u30b0\u30ed\u30fc\u30d6\u30dc\u30c3\u30af\u30b93\u53f0\uff08Li\u7528\uff0cNa\u7528\uff0c\u4e00\u822c\u7528\uff09\uff0c\u6052\u6e29\u5668\uff0c\u30df\u30ad\u30b5\u30fc\uff0c\u30d7\u30ec\u30b9\u6a5f\u7b49\uff09<\/li>\n\n\n\n
  • \u7ba1\u72b6\u7089\uff08\u8a084\u53f0\uff0c850\uff5e1500\u2103\uff09<\/li>\n\n\n\n
  • \u771f\u7a7a\u30fb\u96f0\u56f2\u6c17\u7089\uff08\u8a082\u53f0\uff0c1100\u2103\uff0c2200\u2103\uff09<\/li>\n\n\n\n
  • \u71b1CVD\uff08\u30ac\u30b9\u6d41\u901a\uff09\u8a2d\u5099<\/li>\n\n\n\n
  • \u904a\u661f\u578b\u30dc\u30fc\u30eb\u30df\u30eb<\/li>\n\n\n\n
  • \u5168\u81ea\u52d5\u6bd4\u8868\u9762\u7a4d\u6e2c\u5b9a\u88c5\u7f6e\uff08\u4e00\u70b9BET\uff09<\/li>\n\n\n\n
  • \u7a92\u7d20\u30ac\u30b9\u5438\u7740\u7d30\u5b54\u5206\u5e03\u6e2c\u5b9a\u88c5\u7f6e<\/li>\n\n\n\n
  • \u9060\u5fc3\u5206\u96e2\u6a5f<\/li>\n\n\n\n
  • \u6052\u6e29\u632f\u76ea\u6a5f<\/li>\n\n\n\n
  • \u51cd\u7d50\u4e7e\u71e5\u6a5f<\/li>\n\n\n\n
  • \u771f\u7a7a\u4e7e\u71e5\u6a5f<\/li>\n\n\n\n
  • \u30ac\u30e9\u30b9\u7d30\u5de5\u8a2d\u5099<\/li>\n\n\n\n
  • \u771f\u7a7a\u30e9\u30a4\u30f3<\/li>\n\n\n\n
  • \u6b63\u7acb\u4e09\u773c\u91d1\u5c5e\u9855\u5fae\u93e1<\/li>\n<\/ul>\n\n\n\n

    \u306a\u3069<\/p>\n\n\n\n

    \u203b\uff09XRD\uff0cXPS\uff0c\u96fb\u5b50\u9855\u5fae\u93e1\uff08SEM\uff0cTEM\uff0cSTEM\uff09\u7b49\u306f\u5b66\u5185\u8a2d\u5099\u3092\u5229\u7528\u3057\u3066\u3044\u307e\u3059\u3002<\/p>\n\n\n\n

    <\/p>\n","protected":false},"excerpt":{"rendered":"

    \u7814\u7a76\u5185\u5bb9 \u30de\u30c6\u30ea\u30a2\u30eb\u30b5\u30a4\u30a8\u30f3\u30b9\uff08\u6750\u6599\u7814\u7a76\uff09\u306b\u304a\u3051\u308b\u30a4\u30ce\u30d9\u30fc\u30b7\u30e7\u30f3\u306b\u306f\u5148\u7aef\u7684\u306a\u5206\u6790\u30fb\u8a08\u6e2c\u6280\u8853\u304c\u5927\u304d\u306a\u5f79\u5272\u3092\u679c\u305f\u3057\u3066\u304d\u3066\u304a\u308a\u3001\u4eca\u5f8c\u3082\u305d\u306e\u91cd\u8981\u6027\u306f\u5909\u308f\u308a\u307e\u305b\u3093\u3002\u3057\u304b\u3057 … <\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"_links":{"self":[{"href":"https:\/\/www.jaist.ac.jp\/nmcenter\/labs\/gotoh-www\/wp-json\/wp\/v2\/pages\/11"}],"collection":[{"href":"https:\/\/www.jaist.ac.jp\/nmcenter\/labs\/gotoh-www\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/www.jaist.ac.jp\/nmcenter\/labs\/gotoh-www\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/www.jaist.ac.jp\/nmcenter\/labs\/gotoh-www\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.jaist.ac.jp\/nmcenter\/labs\/gotoh-www\/wp-json\/wp\/v2\/comments?post=11"}],"version-history":[{"count":30,"href":"https:\/\/www.jaist.ac.jp\/nmcenter\/labs\/gotoh-www\/wp-json\/wp\/v2\/pages\/11\/revisions"}],"predecessor-version":[{"id":691,"href":"https:\/\/www.jaist.ac.jp\/nmcenter\/labs\/gotoh-www\/wp-json\/wp\/v2\/pages\/11\/revisions\/691"}],"wp:attachment":[{"href":"https:\/\/www.jaist.ac.jp\/nmcenter\/labs\/gotoh-www\/wp-json\/wp\/v2\/media?parent=11"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}